The October 25/26 weekend event at the Shoreline Amphitheatre in Mountain View will see the pair of Seattle rockers joined by Florence + The Machine, Tom Jones, Norah Jones, Band Of Horses and Neil's wife, Pegi, plus additional guests

Last month, Neil filed for divorce from his wife after 36 years of marriage, but Neil will be on hand to headline while Pegi will perform at the shows with her band, The Survivors.

Pegi co-founded The Bridge School in 1986 with Jim Forderer and help from Dr. Marilyn Buzolich. The first benefit concert, in 1986, raised the money necessary to start the school, which opened in '87.