For the performance, Paisley chose his current radio single "River Bank" but also offered up the title track, debuting it for the first time on national television.

"At certain times, your career should be a party," Paisley has said about the process for making the album, which is due Aug. 26. "River Bank" already is earning its keep as a fun summer sing-along, and based on the loud-and-proud performance of the new song on Kimmel, "Moonshine in the Trunk" will keep that party raging well into the night.