The box set will feature 4-discs, 3 music cds and one DVD.  Geffen records plans to release the set on November 23rd, in time for the Christmas season. 
Some of the highlights include not only the early recordings but also acoustic and electric versions of "Rape Me" as well as some of the final studio recordings from the band from their  January 1993 Rio de Janeiro sessions and Kurt Cobain's home studio demos. 

According to Billboard, the DVD will include 10 previously unreleased clips, including a cover of "Seasons in the Sun" and "Pennyroyal Tea" as well as "the rare 1990 video for 'In Bloom.'"

Here is the leaked (unconfirmed) tracklisting for "With The Lights Out", Nirvana Box Set: 

CD 1:
1. Heartbreaker (3/87 house party in Raymond, WA) 
2. Anorexorcist (4/17/87 KAOS Radio session in Olympia, WA) 
3. White Lace And Strange (4/17/87 KAOS Radio session in Olympia, WA) 
4. Help Me I'm Hungry 
5. Mrs. Butterworth 
6. If You Must (1/23/88 studio session in Seattle, WA) 
7. Pen Cap Chew (1/23/88 studio session in Seattle, WA) 
8. Downer 
9. Floyd The Barber 
10. Raunchola (1/23/88 live performance in Tacoma, WA) 
11. Moby Dick (1/23/88 live performance in Tacoma, WA) 
12. Beans (home recording 1987-1988) 
13. Don't Want It All (possibly home recording 1987-1988) 
14. Clean Up Before She Comes (home recording 1987-1988) 
15. Polly (solo) (possibly home recording 1987-1988) 
16. About A Girl (possibly home recording 1987-1988) 
17. Blandest (June-September 1988 studio session in Seattle, WA) 
18. Dive (Most likely from June 1989 session at Evergreen State College in Olympia, WA) 
19. They Hung Him On A Cross (most likely from August 1989 studio session in Seattle, WA) 
20. Grey Goose (August 1989 studio session in Seattle, WA) 
21. Ain't It A Shame (August 1989 studio session in Seattle, WA) 
22. Token Eastern Song (September 1989 studio session in Seattle, WA) 
23. Even In His Youth (September 1989 studio session in Seattle, WA) 
24. Polly (September 1989 studio session in Seattle, WA)

CD 2:
1. Opinion (09/25/90 KAOS Radio session in Olympia, WA) 
2. Lithium (09/25/90 KAOS Radio session in Olympia, WA) 
3. Been A Son 
4. Sliver (possibly unfinished version from July 11, 1990 session in Seattle, WA) 
5. Where Did You Sleep Last Night 
6. Pay To Play (04/90 studio session in Madison, WI) 
7. Here She Comes Now (04/90 studio session in Madison, WI) 
8. Drain You (possibly from late 1990 demo) 
9. Aneurysm (possibly from 01/01/91 studio session in Seattle, WA) 
10. Smells Like Teen Spirit (demo) (possibly from March 1991 boombox demo) 
11. Breed 
12. Verse Chorus Verse (possibly from March 1991 boombox demo or from Sound City Studios May-June 1991) 
13. Old Age (possibly from March 1991 boombox demo or from Sound City Studios May-June 1991) 
14. Endless, Nameless (most likely from September 3, 1991 radio session) 
15. Dumb (possibly from September 3, 1991 radio session) 
16. D-7 
17. Oh The Guilt (April 1992 studio session in Seattle, WA) 
18. Curmudgeon (April 1992 studio session in Seattle, WA)
19. Return Of The Rat (April 1992 studio session in Seattle, WA) 
20. Smells Like Teen Spirit (Butch Vig Mix) (Sound City Studios May-June 1991)

CD 3:
1. Rape Me (solo) (possibly from October 1992 studio session in Seattle, WA) 
2. Rape Me (possibly from October 1992 studio session in Seattle, WA) 
3. Scentless Apprentice (most likely from January 16, 1993 or January 23, 1993 show) 
4. Heart Shaped Box (January 22, 1993 session in Rio, Brazil) 
5. I Hate Myself And I Want To Die (January 22, 1993 session in Rio, Brazil) 
6. Milk It (January 22, 1993 session in Rio, Brazil) 
7. Moist Vagina (January 22, 1993 session in Rio, Brazil) 
8. Gallons Of Running Alcohol Flows Through The Strip (January 22, 1993 session in Rio, Brazil) 
9. The Other Improv (most likely from January 22, 1993 session in Rio, Brazil) 
10. Serve The Servants 
11. Very Ape (possibly from January 22, 1993 session in Rio, Brazil) 
12. Pennyroyal Tea 
13. Marigold (possibly March 1993 studio session) 
14. Sappy aka Verse Chorus Verse (possibly March 1993 studio session) 
15. Jesus Doesn't Want Me For A Sunbeam 
16. Do Re Mi (Kurt Cobain home demo from March 1994) 
17. You Know You're Right 
18. All Apologies

DVD:
1. Love Buzz 
2. Scoff 
3. About A Girl 
4. Big Long Now 
5. Immigrant Song 
6. Spank Thru 
7. Hairspray Queen 
8. School 
9. Mr. Moustache 
10. Big Cheese 
11. In Bloom 
12. Sappy 
13. School 
14. Love Buzz 
15. Pennyroyal Tea 
16. Smells Like Teen Spirit 
17. Territorial Pissings 
18. Jesus Doesn't Want Me For A Sunbeam 
19. Talk To Me 
20. Seasons In The Sun

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